The influence of thermal degradation on the electrodeposition of aluminium from an air- and water-stable ionic liquid.

نویسندگان

  • Jean-Pierre M Veder
  • Michael D Horne
  • Thomas Rüther
  • Alan M Bond
  • Theo Rodopoulos
چکیده

Aluminium electrodeposition is demonstrated from a thermally degraded ionic liquid solution. NMR and voltammetric analyses established that Al(3+) reduction was remarkably similar to that in non-degraded IL solutions suggesting that the electroactive metal-containing species was unaffected by heat treatment. Electron microscopy revealed a significant grain refinement of the deposited metal.

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عنوان ژورنال:
  • Physical chemistry chemical physics : PCCP

دوره 15 20  شماره 

صفحات  -

تاریخ انتشار 2013